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I don't know about IB because my school never had it, but based on my personal experience with General Biology, taking IB Biology will be very beneficial to you in terms of grades at undergraduate. I frankly don't know which path is better for admission into undergrad, but I highly recommend that you take a high level of Biology before your General Biology in undergrad. Remember, General Biology I and II count for your prerequisites for medical school, so if you can prepare for that in high school, hey why not?
Now, Chemistry is bit different. I think that in many cases, General Chemistry was easy for many students while Organic Chemistry was terrible.
Taking Physics will help before just taking it the first time in undergrad.
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