| | |  | |
04-15-2006, 06:06 PM
|
#46 | | | I’m guessing it’s Zn, Mg, Ca, Na, K, Cs.
What is Gibbs free energy and if delta S is positive, it is spontaneous? | |
| |
04-15-2006, 06:12 PM
|
#47 | | Junior Member
Join Date: Nov 2004
Threads: 16
Posts: 231
| Gibbs free energy is the energy available in the universe for work. If ΔS is positive, that means the entropy is positive and therefore IS SPONTANEOUS. Entropy is the randomness/disorder of the universe, or as my teacher likes to say...spreadiness.
EDIT: I forgot. It also depends on the ΔH. If ΔH is negative and ΔS is positive, the reaction is spontaneous. If ΔS is positive and ΔH is positive, a process is spontaneous at high temperatures, where exothermicity plays a small role in the balance. |
| |
04-15-2006, 06:42 PM
|
#48 | | Junior Member
Join Date: Nov 2004
Threads: 16
Posts: 231
| Oh yeah my question.
Name all five tenets of Dalton's Atomic Theory. |
| |
04-15-2006, 06:49 PM
|
#49 | | | * Elements are made of tiny particles called atoms.
* All atoms of a given element are identical.
* The atoms of a given element are different than those of any other element.
* Atoms of one element can combine with atoms of other elements to form compounds. A given compound always has the same relative numbers of types of atoms.
* Atoms are indivisible in chemical processes. Atoms are not created nor destroyed in chemical reactions. A chemical reaction simply changes the way atoms are grouped together.
Is delta S is negative, is it automatically nonspontaneous no matter what delta H is? | |
| |
04-15-2006, 07:34 PM
|
#50 | | Junior Member
Join Date: Aug 2005
Threads: 25
Posts: 276
| deltaG = delta H - T delta S
No, as long as delta H is very negative (very exothermic), the reaction can be spontaneous. (rxns are spontaneous if delta G is negative).
Q: Alpha, beta, and gamma particles: which type is most penetrating? |
| |
04-15-2006, 07:35 PM
|
#51 | | | gamma particles
Describe Rutherford's experiment. | |
| |
04-15-2006, 09:38 PM
|
#52 | | Member
Join Date: Jul 2005 Location: Florida
Threads: 119
Posts: 551
| his atomic theory describes the atom as having a central positive nucleus surrounded by negative orbiting electrons.
1. A two bulbed flask contains four particles. What is the probability of finding all four particles in only one of the bulbs?
A 0.0625 %
B 0 %
C 6.25 %
D 11.3 %
E 25 % |
| |
04-15-2006, 09:42 PM
|
#53 | | | 1/16 or 0.0625.
Four of the following factors can affect the forward rate of a chemical reaction.
Which one cannot affect this rate?
1) temperature
2) particle size of solid reactants
3) concentration of reactants
4) presence of a catalyst
5) removal of some of the products | |
| |
04-15-2006, 09:43 PM
|
#54 | | Member
Join Date: Jul 2005 Location: Florida
Threads: 119
Posts: 551
| ^^^ wrong, it was 6.25
(so ur question cant be answered yet)
1. Which of the following statements is true?
A In a spontaneous process, DG has a positive value
B The entropy of the universe is increasing
C Exothermic reactions are always spontaneous
D A system at constant temperature cannot experience entropy changes
E For a process to be spontaneous, the number of moles of product must exceed the number of moles of reactant |
| |
04-15-2006, 09:45 PM
|
#55 | | | 0.0625 = 6.25% | |
| |
04-15-2006, 09:46 PM
|
#56 | | Member
Join Date: Jul 2005 Location: Florida
Threads: 119
Posts: 551
| oh sorry lol im out of it |
| |
04-15-2006, 09:48 PM
|
#57 | | Member
Join Date: Jul 2005 Location: Florida
Threads: 119
Posts: 551
| answrr to ur question quickquiz is choice 2) particle size of solid reactants |
| |
04-15-2006, 09:49 PM
|
#58 | | | It’s ok. Yeah I put 2 for that one too. You can the next question ... | |
| |
04-15-2006, 09:50 PM
|
#59 | | Member
Join Date: Jul 2005 Location: Florida
Threads: 119
Posts: 551
| 1. Which of the following statements is true?
A In a spontaneous process, DG has a positive value
B The entropy of the universe is increasing
C Exothermic reactions are always spontaneous
D A system at constant temperature cannot experience entropy changes
E For a process to be spontaneous, the number of moles of product must exceed the number of moles of reactant |
| |
04-15-2006, 09:50 PM
|
#60 | | Junior Member
Join Date: Dec 2005
Threads: 21
Posts: 142
| how would you calculate the probability? assuming the 2 bulbs are the same, i would think that at equilibrium, all gases are present in both bulbs, with the denser gases at the bottom. |
| | All times are GMT -5. The time now is 11:42 AM. |