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Of course it's ok to do so. Though I personally find that I tend to make mistakes towards the end of any test, and since the T/F questions aren't necessarily easy I personally wouldn't put them off 'til the end. But whatever works for you.
I'd say that if you want to try it like that, you should take a few practice tests using that technique to get used to it. However, I agree with dolcevalse that you're probably more likely to mess up a bit towards the end.
Is the propensity to mess-up because of fatigue? Or because the questions at the end of the multiple choice section are more difficult?
To me, the T-F-CE questions are 3x more difficult because it's like having to answer three questions in one! Is a T-F-CE question worth the same amount as a multiple choice question?
SGP, I think it's true for any test that people tend to make mistakes towards the end due to fatigue. Especially for the SAT Chem exam - 85 questions in 60 minutes! Doesn't leave you much time to breathe, or think thoroughly through many things.