@Ranza123, you may think that colleges like to see extra APs, but the colleges say that they don’t. You will hear that at pretty much every college road show and read it on every admissions blog. They would rather that you take a rigorous course load for your school and follow your interests outside of school. If the OP is really interested in psychology s/he should look for ways to explore the field.
(taking the AP to get out of taking Psych 101 is not unreasonable - my point was/is that it won’t help the application)