I can’t imagine she won’t get into UNC and NC State. As I am sure you know, Park and MC is a long shot, as is any merit from either of those schools.
FWIW, Chemistry is very difficult at UNC. Make sure she wants to work to incredibly high standards to do well in it there. Mine is a freshman there and there have been a lot of parent posts about kids struggling in chem, and it is known to be a very tough department. (And all of UNC is pretty tough, tbh.) That said, you obviously know UNC dental is top ranked.
UNCG has a very well know theater program if that is important.