Yeah, my S24 is probably not going to apply to UVA because he didn’t like it nearly as much as William & Mary, and my point to him was UVA is really too hard of a school to get into OOS to bother applying unless he had it as a top few choice. My feeling is it is usually best to leave such colleges to the people who see them as among their top few favorites, and can write honest applications reflecting that enthusiasm. And he can be doing the same at the colleges he really likes.
But of course the OP’s daughter might feel differently. And for the reasons previously stated, if she really liked UVA but wanted a somewhat less selective alternative similar to UVA, then Pitt is definitely worth serious consideration.