How to be in Skaggs School when accepted into Sixth School

You are confusing two very different things.

  1. Sixth College is one of the six colleges that make up the undergraduate system at UCSD. See:

http://provost.ucsd.edu/colleges/

It is independent of you major and there is no good reason to change.

  1. Skaggs seems to be a doctorate of pharmacy program. You cannot apply or be considered for that until you finish your undergraduate degree.