Does applying early helps?

I am applying to several internships and Co-Op, and many of them are due late October.

Does applying ASAP help with getting spots?

Depends on the program. Some may start filling through applications before the due date. It might be worth contacting program coordinators to find out.

It certainly can’t hurt. If your application is great, but all the spots have gone to people who have applied earlier, you’re not getting in.