Not really adding much to the conversation here, but I have one more heartening data point to add. My D, also an unhooked white female (from New England, no less – perhaps the worst possible demographic), applied to several top tier LACs three years ago with very similar stats, and decent but not especially remarkable ECs. She was accepted into Middlebury, Bowdoin and Carleton and waitlisted at Williams. So, take heart! I think your D has a great shot at getting into at least some of the highly selective schools to which she applies. It’s easy to forget on these forums that stats like your D’s do not grow on trees. That 33 ACT score is top 1%. She’ll be fine!
And, as others have emphasized, there are some really tremendous LACs out there that are one notch down in selectivity from those in the top 15 or so (and some of them even offer merit aid!). In particular, you can find a lot of quality bang for your selectivity buck if you’re willing to look outside New England.